Thermal stability of ionic solids: A melting points survey

نویسندگان

چکیده

While predictive correlations of the melting points organic solids are well-established and reliable, ionic less understood. We provide a comprehensive survey related literature for which shows that primary factors to consider ambient temperature values formation enthalpies distances among ions as enshrined in their crystal structures. These conclusions from standard thermodynamic analyses supported by an independent current machine-learning program. This result contrasts with common belief lattice energies leading factor melting. idea is confounded irrelevant (but generally overwhelming) inclusion energy gaseous evaluation through thermochemical cycles. The simple metal halides correlated per halide ion determined structures rather than energies. As formula units increase chemical structural complexity relations also become more complex.

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ژورنال

عنوان ژورنال: Chemical thermodynamics and thermal analysis

سال: 2022

ISSN: ['2667-3126']

DOI: https://doi.org/10.1016/j.ctta.2022.100092